Brimstone (1998)

Ezekial Stone, a former cop, planted evidence on his wife's rapist whom was subsequently convicted. While incarcerated the rapist was killed, thus rendering Stone a murder. Later, Stone was himself killed by a criminal. He is sent to Hell for his crime. However, 113 evil souls have escaped, and the Devil sends him back to Earth to recover them. Both Stone and the escaped souls can only be harmed or killed by each other, and they can be sent back to Hell if their eyes (the "windows to the soul") are destroyed. If Stone can recover all 113, then he'll be given a second chance at life...or so the Devil says.