The Man from U.N.C.L.E. (1964)

Napoleon Solo (Robert Vaughn) and Illya Kuryakin (David McCallum) are the two Agents of the United Network Command for Law Enforcement (U.N.C.L.E.), who fight evil (primarily an organization of bad people called, T.H.R.U.S.H.) and use charm, wit, and a never ending assortment of gadgets.